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Citation: SHI Xiao-Bo, WANG De-Xian, WAN Ping-Nan, LI Chun-Gen, WANG Sai-Ying. Solid State Synthesis of Transition Metal Molybdovanadophosphate Nanoparticles[J]. Chinese Journal of Applied Chemistry, ;2003, 20(9): 857-861. shu

Solid State Synthesis of Transition Metal Molybdovanadophosphate Nanoparticles

1.
College of Chemistry, Jiangxi Normal University, Nanchang 330027

Corresponding author: SHI Xiao-Bo,
Received Date: 24 January 2003
Available Online: 21 April 2003
Fund Project: 国家自然科学基金资助项目(20261003) (20261003)

Four polyoxometalate particles H₃MPMo₁₀V₂O₄₀·xH₂O(M=Co²⁺,Ni²⁺,Cu²⁺,Zn²⁺) were synthesized by solid-state reaction at room temperature. Their structures, particle sizes, thermal properties and surface properties were investigated by IR, UV, XRD, TEM, TG-DTA and TPR techniques. The results show that these four polyoxometate particles have Keggin structure with size being 32~42 nm. The thermal stability of the polyoxometalates appeared decreased, but surface activity increased significantly, when they are in nanoparticles form.
- nanoparticle,
- polyoxometate,
- Keggin structure,
- solid-state reaction
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