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Citation: LIU Shu-Fen. Synthesis and Property of A Polymeric Pseudo-Crown Ether (POCE)[J]. Chinese Journal of Applied Chemistry, ;2003, 20(10): 982-985. shu

Synthesis and Property of A Polymeric Pseudo-Crown Ether (POCE)

LIU Shu-Fen ^,

1.
Department of Chemistry, Yantai Normal College, Yantai 264025

Corresponding author: LIU Shu-Fen,
Received Date: 26 January 2003
Available Online: 29 July 2003

A phenolic polymeric pseudo crown ether(POCE) was directly synthersized from phenoxy ethanol and formaldehyde in one step. The phenolic resinification was studied by infrared spectrometry. The results show that besides the proportion of phenoxy ethanol to formaldehyde, reaction temperature and time, the crux is the amount of concentrated sulphuric acid used in phenol fromaldehyde condensation when 2-phenoxy ethanol is used as monomer. The polymer has good adsorption properties for Na⁺, K⁺, Ca²⁺, Sr²⁺, Hg²⁺, Cu²⁺, the adsorption capacities are 1.525, 0.849, 2.027, 0.709, 0.815 and 0.406 mmol/g, respectively.
- polymeric pseudo crown ether,
- synthesis,
- adsorption,
- FTIR spectra
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Synthesis and Property of A Polymeric Pseudo-Crown Ether (POCE)

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com