Citation:
WANG Ping-Hua, YAN Man-Qing. Preparation, Structure and Mechanical Properties of PP/PMMA/CaCO3 Nanocomposites[J]. Chinese Journal of Applied Chemistry,
;2003, 20(11): 1066-1070.
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The stearic acid treated CaCO3 nanoparticles(abbraviated particle A) and their PMMA covered ones(abbraviated particle B) were blended with polypropylene(PP) to give PP/CaCO3 and PP/PMMA/CaCO3 nanocomposites. The size and dispersion of surface treated CaCO3 nano-particles were studied by TEM. The results showed that PMMA/CaCO3 composited nanoparticles were relatively homogeneously dispersed in PP matrix. The crystallization behavior of the nanocomposites were investigated by means of DSC and WAXD measurements. The β-type crystal of PP was observed, could be due to the heterogeneous nucleation of PP with PMMA/CaCO3 particles on blending. The mechanical propertyes of the PP/PMMA/CaCO3 nanocomposites prepared were greatly improved.
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Keywords:
- surface treatment,
- nanocomposites,
- mechanical properties,
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