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Citation: LI Xia, LIANG Yan. Photochromism of the Ternary System, Containing Lanthanide Ion, N,N-Bis(2-pyrrolidone-1-methylene)-β-alanine and o-Phenathroline[J]. Chinese Journal of Applied Chemistry, ;2003, 20(12): 1196-1199. shu

Photochromism of the Ternary System, Containing Lanthanide Ion, N,N-Bis(2-pyrrolidone-1-methylene)-β-alanine and o-Phenathroline

LI Xia ^a,, ,
LIANG Yan ^b

1.
a Department of Chemistry, Capital Normal University, Beijing 100037;
2.
b Department of Chemistry, Beijing Normal University, Beijing

Corresponding author: LI Xia,
Received Date: 25 April 2003
Available Online: 20 August 2003
Fund Project: 北京市自然科学基金(2022007) (2022007)

The RE³⁺-N,N-bis(2-pyrrolidone-1-methylene)-β-alanine(PMA)-o-phenathroline(phen) ternary systems were prepared. The ternary systems were found to exhibit photochromic property. Under illumination of sunlight or mercury arc lamp in an aqueous solution their color could change from yellow to green and faded back to the original yellow color, when the illumination was shutting down. The effect of pH value of the aqueous solution on the photochromism of the system has been investigated in relation with the excitation, emission of the Eu³⁺-PMA-phen system and absorption spectra of the Dy³⁺-PMA-phen system.
- lanthanide ion,
- bis-(pyrrolidone-methylene)-alanine,
- phenathroline,
- ternary system,
- photochromism
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