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Citation: XIAO Yi, LAN Zhi-Li, YIN Du-Lin, HUANG Hong-Mei, MAO Li-Qiu. Synthesis of Diallylmethylamine by Phase Transfer Catalysis[J]. Chinese Journal of Applied Chemistry, ;2004, 21(8): 818-820. shu

Synthesis of Diallylmethylamine by Phase Transfer Catalysis

1.
Institute of Fine Catalysis and Synthesis, Hu'nan Normal University, Changsha 410081

Corresponding author: YIN Du-Lin,
Received Date: 28 September 2003
Available Online: 25 April 2004
Fund Project: 国家自然科学资金资助项目(29972011) (29972011)

Synthesis of diallylmethylamine from lower concentration methylamine water solution and allylchloride has been performed using polyglycol-400(PEG-400) as phase transfer catalyst. The results show that the reaction time can be efficiently shortened and product yield can be significantly increased. The orthogonal experimental method has been used to optimize the experiment conditions. The optimal condition are as follows:PEG-400 phase transfer catalyst, mole ratios of allylchloride:methylamine=2.2:1, the two periods of reaction temperature and time 20℃(1 h) and 60℃(6 h), diallylmethylamine is obtained in 75.6% yield. The product is characterized by IR, GC-MS and ¹H NMR.
- diallylmethylamine,
- phase transfer catalysis,
- polyglycol-400
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