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Citation: DUAN Ming, HU Xing-Qi, . Synthesis of Cationic Hydrophobically Modified Acrylamide Copolymers[J]. Chinese Journal of Applied Chemistry, ;2004, 21(8): 806-809. shu

Synthesis of Cationic Hydrophobically Modified Acrylamide Copolymers

DUAN Ming ^a ,
HU Xing-Qi ^b ,
^b,, ,
^b,,

1.
Department of Chemical Engineering, Southwest Petroleum Institute, Chengdu 610500
2.

Corresponding author: , ,
Received Date: 25 September 2003
Available Online: 13 April 2004
Fund Project: 油气藏地质及开发工程国家重点实验室开放基金(PLN0120) (PLN0120)四川省重点学科建设基金(SZD0413)资助 (SZD0413)

A surface-active macromonomer(VBDMOAC) was synthesized from p-vinyl benzyl chloride and octadecyl dimethyl amine. Its structure was identified by measurement of chlorine content, IR and ¹H NMR. Its cmc and γ_cmc were determined to be 1.19×10^-4 mol/L and 41.4 mN/m, respectively. Compared to AM-AA copolymer prepared in the same conditions, the intrinsic viscosities of the copolymers obtained from ternary polymerization of VBDMOAC, AM and AA in aqueous solvent showed that VBDMOAC have a higher polymerization activity. The terpolymer (VBDMOAC-AM-AA) was verified by its UV band at 224 nm and IR band at 1454 cm^-1.
- hydrophobically modified,
- surface-active macromonomer,
- synthesis
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