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Citation: LUO Shi-Ping, GUO Deng-Feng, QIU Zhao-Rong, LU Lu-De. Synthesis of Butyl Acetate Catalyzed by Silica-Supported Recovered Perfluorosulfonic Acid Resin[J]. Chinese Journal of Applied Chemistry, ;2004, 21(10): 1072-1074. shu

Synthesis of Butyl Acetate Catalyzed by Silica-Supported Recovered Perfluorosulfonic Acid Resin

1.
a School of Chemical Engineering, Nanjing University of Scienceand Technology, Nanjing 210094;
2.
b Jiangsu Provincial Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou

Corresponding author: LUO Shi-Ping,
Received Date: 31 October 2003
Available Online: 30 January 2004
Fund Project: 江苏省教育厅资助项目(KJS02113) (KJS02113)

The used perfluorosulfonic acid ion-exchange membrane was treated to recycle the perfluorosulfonic acid resin. The perfluorosulfonic acid resin/silica composite catalysts were prepared by a sol-gel method and characterized by FTIR, TG, BET_measurements. The composite catalysts obtained were used in esterification of HAc and butyl alcohol. The results showed that at n(HAc):n(butyl alcohol)=1.3:1.0, 3 g catalyst, 110℃ and 2 h, butyl acetate could be obtained in yield of 92.4%.
- solid acid,
- perfluorosulfonic acid resin/silica composite catalyst,
- butyl acetate,
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