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Citation: LI Xia, JIN Qiong-Hua. Synthesis and Crystal Structure of[Nd(C₄H₃OCOO)₂·NO₃·C₁₀H₈N₂]₂Complex[J]. Chinese Journal of Applied Chemistry, ;2004, 21(10): 1060-1062. shu

Synthesis and Crystal Structure of[Nd(C₄H₃OCOO)₂·NO₃·C₁₀H₈N₂]₂Complex

LI Xia ^, ,
JIN Qiong-Hua

1.
Department of Chemistry, Capital Normal University, Beijing 100037

Corresponding author: LI Xia,
Received Date: 8 October 2003
Available Online: 30 December 2003
Fund Project: 北京市自然科学基金项目(2022007) (2022007)北京市科技新星项目(9528719800) (9528719800)

The complex[Nd(C₄H₃OCOO)₂·NO₃·C₁₀H₈N₂]₂ was synthesized from Nd(NO₃)₃·nH₂O, 2-furancarboxylic acid(C₄H₃OCOOH), and 2,2'-bipyridine(C₁₀H₈N₂]₂). The unit cell is triclinic and of Pī symmetry. Unit cell parameters are:P1, a=0.992 18(17) nm, b=1.023 05(17) nm, c=1.114 4(3) nm, α=86.778(8)°, β=76.153(5)°, γ=70.363(14)°, M=584.58, V=1.037 3(4) nm³, Z=1, D_calc=1.877 Mg/m³, T=293(2) K. The final R=0.061 8, wR=0.164 4. Each Nd³⁺ ion is coordinated by five O atoms of four furancarboxylate groups, two O atoms of nitrate and two N atoms of 2,2'-bipyridine molecule, with a coordination number of 9. The four carboxylate groups coordinate in two modes:bridging and bridging chelating. The two Nd³⁺ ions in the dimer are held together by four carboxylate groups of furancarboxylic acid.
- neodymium,
- furancarboxylic acid,
- bipyridine,
- composite ligand complex,
- crystal structure
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Synthesis and Crystal Structure of[Nd(C₄H₃OCOO)₂·NO₃·C₁₀H₈N₂]₂Complex