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Citation: WEI Chang-Mei, XU Bin, ZHU Hong-Jun, WANG Jin-Tang. One-step Synthesis of 4-Nitrophenyl Ferulate in Presence of DCC as Catalyst[J]. Chinese Journal of Applied Chemistry, ;2004, 21(11): 1184-1186. shu

One-step Synthesis of 4-Nitrophenyl Ferulate in Presence of DCC as Catalyst

1.
Department of Applied Chemistry, Nanjing University of Technology, Nanjing 210009

Corresponding author: WANG Jin-Tang,
Received Date: 15 December 2003
Available Online: 5 June 2004
Fund Project: 江苏省社会发展基金(BS2002041)资助项目 (BS2002041)

4-Nitrophenyl ferulate was synthesized in one-step without the protection of the hydroxyl of ferulic acid in the presence of 1,3-dicyclohexylcarbodiimide(DCC) as the catalyst. Thus, 15.20 g of ferulic acid reacted with 18.07 g of 4-nitrophenol for 24 h at room temperature in the presence of 22.44 g of DCC. The crude product was recrystallized from CHCl₃ to give 16.00 g of 4-nitrophenyl ferulate and the yield was 82.5%. Elemental analysis, IR and ¹H NMR techniques were used to prove the structure of the product.
- nitrophenyl ferulate,
- dicyclohexylcarbodiimide,
- catalystic,
- esterification
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