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Citation: CHEN Hai-Qun, ZHU Jun-Wu, WANG Hai-Jing, YANG Xu-Jie, LU Lu-De, WANG Xin. Inhibition of Phosphine Liberation from Red Phosphorus[J]. Chinese Journal of Applied Chemistry, ;2004, 21(11): 1141-1144. shu

Inhibition of Phosphine Liberation from Red Phosphorus

CHEN Hai-Qun ^a,b ,
ZHU Jun-Wu ^a ,
WANG Hai-Jing ^a ,
YANG Xu-Jie ^a ,
LU Lu-De ^a ,
WANG Xin ^a,,

1.
a Material Chemistry Laboratory, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094;
2.
b Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou

Corresponding author: WANG Xin,
Received Date: 1 December 2003
Available Online: 20 March 2004
Fund Project: 江苏省科技厅高技术研究资助项目(BG2002015) (BG2002015)江苏高校高新技术产业发展资助项目(JH02007) (JH02007)

The influences of trace materials on the liberation of PH₃ from red phosphorus and the way to slow down the liberation have been studied by headspace gas chromatography and accelerated aging tests. It has been found that the liberation of PH₃ from commercial red phosphorus is mainly due to its reaction with water. Trace amount of metal ions such as iron, copper, nickel and chromium greatly affected the liberation of PH₃. It is found that addition of 1%(mass fraction) nano-magnesium hydroxide can slow down the PH₃ liberation significantly and result in a yield of less than 0.4 mg/(m³·d) from the oven-dried red phosphorus, without changing the dispersibility and fluidity of the phosphorus.
- red phosphorus,
- accelerated aging tests,
- phosphine
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