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Citation: XING Yong-Heng, XU Ji-Qing, GUO Chun-Xiao, BAI Feng-Ying, YANG Guan-Di, XING Yan, LIN Yong-Hua, JIA Heng-Qing. Synthesis, Spectroscopy and Electronic Structure of Mo/S Complex Containing Citrate Ligands[J]. Chinese Journal of Applied Chemistry, ;2004, 21(12): 1305-1309. shu

Synthesis, Spectroscopy and Electronic Structure of Mo/S Complex Containing Citrate Ligands

1.
a College of Chemistry and Chemical Engineeing, Liaoning Normal University, Dalian 116029;
2.
b College of Chemistry, Jilin University, Changchun;
3.
c Institute of Theoretical Chemistry, Jinlin University, Changchun;
4.
d Changchun Institute of Applied Chemistry, Chinese Academy of Scienses, Changchun

Corresponding author: XING Yong-Heng,
Received Date: 17 January 2004
Available Online: 14 April 2004
Fund Project: 国家基础研究规划项目(2001CB108906) (2001CB108906)国家自然科学基金资助项目(20271021和20333070) (20271021和20333070)

The synthesis and structure of a Mo/S complex containing citrate ligands are reported. The complex was characterized by means of elemental analysis, IR, UV-Vis, EPR, NMR and TG-DTA. The electronic structure of the complex anion is discussed using the EHMO method. A corelation between the bonding order and the IR band of the C=O group was established, that is, the bonding orders 0.914, 0.869 and 0.809 correspond to vibration adsorption peaks of the carboxyl group at 1 606,1 587 and 1 550 cm^-1, respectively, which helped explain why the IR band for the carboxyl groups are wide and split.
- Mo/S complex,
- citrate,
- spectral properties,
- electronic structure
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