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Citation: LIANG Qiang, HAN Ai-Xia, ZHANG Fu-Shi. Synthesis and Application of Manganese(Ⅱ)-Tetrasulfophthalocyanine[J]. Chinese Journal of Applied Chemistry, ;2004, 21(12): 1290-1294. shu

Synthesis and Application of Manganese(Ⅱ)-Tetrasulfophthalocyanine

LIANG Qiang ^a,b ,
HAN Ai-Xia ^a,c ,
ZHANG Fu-Shi ^a,,

1.
a Ministry of Education Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084;
2.
b Department of Chemistry, Normal College, Qingdao University, Qingdao;
3.
c Department of Chemistry, Qinghai University, Xining

Corresponding author: ZHANG Fu-Shi,
Received Date: 29 December 2003
Available Online: 10 July 2004
Fund Project: 国家自然科学基金重点项目(20333080) (20333080)

Manganese(Ⅱ)-tetrasulfophthalocyanine(b) was synthesized from the reaction of manganous chloride with tetrachlorosulfonylphthalocyanine(a) obtained from phthalocyanine(H₂Pc) by chlorosulfonation with chlorosulfonic acid. Products (a) and (b) were characterized by UV-Vis, ¹H NMR, FT-IR, elemental analysis and TGA. The catalytic property of (b) was studied as hydrogen peroxide enzyme-mimic in aqueous solution by catalytical spectrophotometry. The result shows that the maximum absorption wavelength of (b) for the system of (b)+phenol+4-aminoantipyrene(4-AAP)+H₂O₂ is at 508 nm, well close to that of the system catalyzed by horse radish peroxydase(HRP), and the absorption intensity increases with the increase of the concentration of hydrogen peroxide. Indicating compound (b) has similar catalytic activity as HRP.The linear regression equation for hydrogen peroxide determination was A=(0.489 97±0.055 27)+(0.021 98±0.002 02)×10³[H₂O₂], with correlation coefficient R=0.991 7, and linear range of 1~50 mmol/L. The linear regression equation for glucose determination(coupled with GOD catalytic system) was A=(0.091 55±0.014 93)+(0.022 64±0.001 77)×10³[glucose], with correlation coefficient R=0.990 9, and linear range of 1~14 mmol/L.
- tetrachlorosulfonylphthalocyanine,
- manganese(Ⅱ)-tetrasulfophthalocyanine,
- synthesis,
- mimic hydrogen peroxidase
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