Citation:
SU Xiu-Li, LIU Hong-Tao, ZHANG Xiao-Gang. Electrochemical Behavior of CoTiO3 Modified K2FeO4 Electrodes[J]. Chinese Journal of Applied Chemistry,
;2004, 21(12): 1249-1252.
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CoTiO3 nanoparticles were prepared by a sol-gel method and used for modification of K2FeO4 electrodes. The electrochemical tests showed that the modified electrode provided both the longest high discharge plateau and satisfactory discharge capacity with addition of 20%(mass fraction) CoTiO3. Co(Ⅱ) salt could be oxidized to Co(Ⅲ) by K2FeO4, which resulted in the loss of active material K2FeO4. However, the presence of Co(Ⅲ) could efficiently improve the discharge plateau of K2FeO4 electrodes.
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Keywords:
- K2FeO4,
- CoTiO3,
- modified electrode,
- discharge potential
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