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Citation: YAN Hao, HU Wang-Ming, SHEN Lü-Ming. Gas Chromatographic Analysis of Products from Reaction of Phenol with Dimethyl Carbonate[J]. Chinese Journal of Applied Chemistry, ;2005, 22(11): 1271-1273. shu

Gas Chromatographic Analysis of Products from Reaction of Phenol with Dimethyl Carbonate

1.
Department of Chemical Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: HU Wang-Ming,
Received Date: 22 December 2004
Available Online: 27 May 2005

Diphenyl carbonate(DPC) as an important product was used for synthesizing polycarbonate instead of phosgene.To detect the reaction process and products,a gas chromatographic method for analyzing the related six compounds(methanol,DMC,anisole,MPC,phenol,DPC) during the transesterification of phenol with dimethyl carbonate(DMC) was first proposed and described.All the compounds mentioned above were well separated through a FFAP chromatographic capillary column.A good linear relationship between the injection amount versus peak area was observed with the correlation coefficients of 0.996 3,0.994 6,(0.996 9),0.998 1,0.977,0.996 1,and the detection limits of six related compounds were founded to be 0.114,0.171,0.041 0,0.080 4,0.051 9,0.075 8 g/L respectively.
- diphenyl carbonate,
- dimethyl carbonate,
- gas chromatography
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