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Citation: CHEN Zhen-Feng, WANG Xian-Wen, HUANG Ling, ZHOU Jian, LIANG Hong, LI Yan. Synthesis and Properties of Hexanuclear Copper(Ⅰ) Cluster Containing Sulphur[Cu₆(C₅H₄NS)₆] via a New Method[J]. Chinese Journal of Applied Chemistry, ;2005, 22(11): 1268-1270. shu

Synthesis and Properties of Hexanuclear Copper(Ⅰ) Cluster Containing Sulphur[Cu₆(C₅H₄NS)₆] via a New Method

1.
a College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004;
2.
b Institute of Chemistry, Chinese Academy of Sciences, Beijing

Corresponding author: LIANG Hong,
Received Date: 15 December 2004
Available Online: 10 April 2005
Fund Project:

A hexanuclear copper(Ⅰ) cluster[Cu₆(C₅H₄NS)₆] was synthesized by means of the hydrothermal reaction of[Cu(PPh₃)₂(MeCN)₂]ClO₄ with(2-mercaptopyridine-1-oxide) in the presence of 2-butanol,Et₃N and water and characterized by elemental analysis,IR,TGA and solid state fluorescence spectroscopy as well as X-ray diffractometry.The crystallographic data for the title complex,C₁₅H₁₂Cu₃N₃S₃,are M_r=521.08,monoclinic space group P2(1)/n and the cell parameters are:a=0.958 59(6) nm,b=(1.604 85(12) nm),(c=)0.122 712(10) nm,β=108.863(2)°,V=1.786 4(2) nm³,Z=4,D_c=(1.937 Mg/m³),R₁=0.030 1,ωR₂=0.031 5(I>2σ(I)),F(000)=1 032,μ=3.890 mm^-1,R(int)=0.050 1,S=0.598.The title complex exhibits highly thermal stability and strong low energy fluorescence((λ=744 nm) when it is irradiated by the light(λ=468 nm) in solid state at room temperature.
- hexanuclear copper(Ⅰ)cluster,
- hydrothermal synthesis,
- crystal structure,
- thermal stability,
- luminescence
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Synthesis and Properties of Hexanuclear Copper(Ⅰ) Cluster Containing Sulphur[Cu6(C5H4NS)6] via a New Method

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of Hexanuclear Copper(Ⅰ) Cluster Containing Sulphur[Cu₆(C₅H₄NS)₆] via a New Method