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Citation: TAO Jian-Qin, SUN Chong, ZHANG Li-Min, FEI Zheng-Hao, GU Zhi-Guo. Mechanism for Preparation of Condensed Rings Compounds Containing Nitrogen Analyzed with HPLC and ESI-MS[J]. Chinese Journal of Applied Chemistry, ;2005, 22(11): 1234-1238. shu

Mechanism for Preparation of Condensed Rings Compounds Containing Nitrogen Analyzed with HPLC and ESI-MS

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a Department of Chemistry, Yancheng Teacher's College, Yancheng 224002;
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b Institute of Environmental Science, Key Laboratory of Environmental Engineering of Jiangsu Province, Nanjing;
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c Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing

Corresponding author: TAO Jian-Qin,
Received Date: 2 December 2004
Available Online: 20 June 2005
Fund Project: 江苏省教育厅自然科学基金项目(No.02KJB150010) (No.02KJB150010)江苏省环境科学研究院重点实验室开放基金项目(No.KF0407) (No.KF0407)

The interactions between phen-5,6-dione and ethyldiamine or cis-diaminomaleonitrile were studied via high performance liquid chromatography and electrospray ionization mass spectrometry respectively.The results show that the intermediate from the addition reaction between the carbonyl and amine groups formed first,it was further dehydrated to form the double bond.And if a conjugated system could be formed,the resulting intermediate would be dehydrogenated further into conjugated compounds of condensed rings.
- ESI-MS,
- high performance liquid chromatography(HPLC),
- mechanism of reaction,
- ligand dpq,
- ligand ttd
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