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Citation: SHI Zai-Feng, REN Xue-Chang, LIU Donga, KONG Ling-Ren. Oxidative Degradation of Organic Compounds with a New Fenton Reagent[J]. Chinese Journal of Applied Chemistry, ;2005, 22(12): 1300-1303. shu

Oxidative Degradation of Organic Compounds with a New Fenton Reagent

1.
a State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210093;
2.
b Department of Chemistry, Hainan Normal University, Haikou

Corresponding author: SHI Zai-Feng,
Received Date: 22 December 2004
Available Online: 14 September 2005
Fund Project: 国家"八六三"计划项目(2002AA601250) (2002AA601250)高等学校博士学科点专项科研基金(20020284044) (20020284044)

HClO was produced from NaClO or Ca(ClO)₂ under acidic condition,and organic compounds in wastewater were degraded via Fenton reaction with HClO instead of H₂O₂.Experimental results indicate that the reduction of chemical oxygen demand(COD) were 40%,38%,12%,50%,and 73% for β-naphthol,salt R a intermediate of dye,dihydroxy salt R,acid red (dye),and wastewater,respectively when the reactions had run for 4 h at a pH of 1.7.In comparison,the COD reduction of β-naphthol and salt R were 10.2% and 16.2%,lower than 23.4% and 18.1% with H₂O₂,while the Fenton reaction time was 1 h.However,under UV light,the corresponding COD reduction rates were 35.0% and 23.1% with HClO vs 29.8% and 21.3% with H₂O₂.These results show that it is feasible to use HClO instead of H₂O₂ in Fenton reaction.
- hypochloric acid,
- Fenton reaction,
- degradation of organic compounds
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