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Citation: HE Miao, ZHOU Hai-Xia, LIU Chun-Sheng, LUO Gen-Xiang. Synthesis of Benzaldehyde 1,2-Propylene Acetal Catalyzed by Polyaniline Doped with Ferric Chloride[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 343-345. shu

Synthesis of Benzaldehyde 1,2-Propylene Acetal Catalyzed by Polyaniline Doped with Ferric Chloride

1.
Petrochemical Engineering School, Liaoning University of Petroleum and Chemical Technology, Fushun 113001

Corresponding author: LUO Gen-Xiang,
Received Date: 16 May 2005
Available Online: 30 June 2005

A new enviromental-freiendly catalyst,PAn-FeCl₃ was prepared.Benzaldehyde 1,2-propylene acetalization was carried out with benzaldehyde and 1,2-propylene alcohol in the presence of polyaniline doped with ferric chloride.Factors influencing the product yield were discussed and optimum conditions were found.Experimental result shows that polyaniline doped with ferric chloride is an excellent catalyst.Under the conditions where a ratio of n(benzaldehyde):n(1,2-propylene)=1:1.4,ω(polyaniline doped with ferric chloride)=0.98%,cyclohexane 14 mL and reaction time 2.0 h,the yield of benzaldehyde 1,2-propylene acetal can reach 93%.
- acetal,
- ferric chloride,
- polyaniline,
- dope
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