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Citation: WANG Yun-Yan, CAI Ya-Hua, YAN Chao-Guo. Syntheses and Metal Ions Recognition of Dentritic Calix[n]arenes(n=6,8) Amide Derivatives[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 278-282. shu

Syntheses and Metal Ions Recognition of Dentritic Calix[n]arenes(n=6,8) Amide Derivatives

1.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Corresponding author: YAN Chao-Guo,
Received Date: 26 May 2005
Available Online: 25 August 2005
Fund Project: 江苏省教育厅科研基金项目(04KJB150156) (04KJB150156)

Dendritic p-t-butylcalix[n] arene amide derivatives with terminal amino groups of the first and second generations were synthesized from the ammonolysis of ethyl calixylacetate with 1,6-diaminohexane and Michael addition of methyl acrylate.Their structures were confirmed by IR,¹H NMR.The recognition properties of these amide derivatives for several kinds of metal ions were studied with UV-Vis spectroscopy.In the processes of recognition they showed a great affinity for soft Ag⁺ and UO₂²⁺ ions and formed 1:2 or 1:3 stoichiometric complexes.
- alixarene,
- dendritic compound,
- amide,
- metal ion recognition,
- UV-Vis spectrum
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