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Citation: ZHANG Ya-Ran, ZHAO Ji-Quan, HE Le-Qin, ZHANG Song-Mei, WU Wei-Peng. Synthesis and Characterization of Complexes of Mn(Ⅲ),Fe(Ⅲ) and Ni(Ⅲ) with N,N'-Bis(methyl 3-formyl-4-hydroxybenzoate)-1,2-diaminocyclohexane[J]. Chinese Journal of Applied Chemistry, ;2006, 23(4): 450-452. shu

Synthesis and Characterization of Complexes of Mn(Ⅲ),Fe(Ⅲ) and Ni(Ⅲ) with N,N'-Bis(methyl 3-formyl-4-hydroxybenzoate)-1,2-diaminocyclohexane

1.
School of Chemical Engineering, Hebei University of Technology, Tianjin 300130

Corresponding author: ZHAO Ji-Quan,
Received Date: 14 June 2005
Available Online: 9 August 2005
Fund Project: 国家自然科学基金资助项目(20376017) (20376017)

A new schiff base ligand was synthesized by the condensation reaction of methyl 3-formyl-4-hydroxybenzoate with 1,2-diaminocyclohexane under N₂ in absolute ethanol.The ligand first reacted with Mn(OAc)₂·4H₂O,and then the mixture was exposed to air and treated by LiCl in absolute ethanol to obtained a Mn(Ⅲ) complex.Two Fe(Ⅲ) and Ni(Ⅱ) complexes were also prepared by the reaction of the ligand with the corresponding metal chloride salts.The new ligand and the complexes were characterized by elemental analysis,¹H NMR and IR.
- N,N'-bis (methyl formylhydroxybenzoate) diaminocyclohexane,
- schiff base,
- metal complex
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