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Citation: HU Yu-Jun, BAO Yong-Zhong, HUANG Zhi-Ming, WENG Zhi-Xue. Pillaring and Polymerization of Vinylbenzene Sulfonate in the Interlayer of Hydrotalcite[J]. Chinese Journal of Applied Chemistry, ;2006, 23(6): 672-675. shu

Pillaring and Polymerization of Vinylbenzene Sulfonate in the Interlayer of Hydrotalcite

1.
State Key Laboratory of Polymer Reaction Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: BAO Yong-Zhong,
Received Date: 16 July 2005
Available Online: 30 October 2005

Vinylbenzene sulfonate(VBS) pillared hydrotalcite(VBS-HT) was obtained by the ion-exchange reaction of VBS with nitrate anion pillared HT(NO₃-HT),which was previously prepared by a co-precipitation method.The polymerization of pillaring VBS was conducted.The structure of VBS pillared HT and its polymerization product were characterized by means of X-ray diffraction,infrared spectrum and elemental analysis.It was found that well pillaring of VBS in HT could be achieved via ion-exchange reaction,and the interlayer spacing increased from 0.90 nm for NO₃-HT to 1.83 nm for VBS pillared HT.The interlayer spacing was further increased to 1.94 nm after VBS was polymerized in the interspace of HT.
- hydrotalcite,
- vinylbenzene sulfonate,
- pillar,
- polymerization
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