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Citation: DAI Yan-Feng, WEN Hui-Min, LI Feng-Yi. Supported Liquid-phase Platinum Catalyst for Hydrosilylation of 3-Chloropropene[J]. Chinese Journal of Applied Chemistry, ;2006, 23(6): 602-606. shu

Supported Liquid-phase Platinum Catalyst for Hydrosilylation of 3-Chloropropene

1.
Department of Chemistry, Nanchang University, Nanchang 330047

Corresponding author: LI Feng-Yi,
Received Date: 18 July 2005
Available Online: 13 December 2005
Fund Project: 江西省教育厅高校科技基金项目(赣教技字[2005]34号) (赣教技字[2005]34号)

The preparation of supported liquid-phase platinum catalyst,and its catalytic property for hydro-silylation reaction of 3-chloropropene were studied.The catalyst displays a high activity and stability under atmospheric pressure for hydrosilylation of 3-chloropropene.The effects of temperature,feeding rate of reactants,and quantity of catalyst used on the hydrosilylation reaction were investigated.At 90℃,the single conversion of 3-chloropropene can be 96.2%,while the selectivity and yield of (3-chloropropyl)methyldichlorosilane can reach 86.9% and 83.6% respectively.The catalyst can be used for 15 h without too loss in term of catalytic activity.The catalytic activity for the hydrosilylation can be improved when modified by Gd.
- supported liquid-phase platinum catalyst,
- hydrosilylation,
- catalysis,
- chloropropene
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