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Citation: GAO Fu-Tang, ZHANG Xiao-Lei, FENG Jian-Yan, WANG Zhao-Yan. Synthesis and Properties of Acrylic Resin Modified by Hydroxyl Silicon Oil[J]. Chinese Journal of Applied Chemistry, ;2006, 23(7): 790-793. shu

Synthesis and Properties of Acrylic Resin Modified by Hydroxyl Silicon Oil

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a Shaanxi University of Science and Technology, Xianyang;
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b China Leather & Footwear Industry Research Institute, Beijing 100016

Corresponding author: ZHANG Xiao-Lei,
Received Date: 21 August 2005
Available Online: 8 January 2006
Fund Project: 陕西省自然科学基金(2003B08)资助项目 (2003B08)

With ammonium persulfate as initiator,mixture of sodium dodecyl benzene sulfonate(SDBS) and nonionic emulsifier alkyl ethyleue oxide as compound emulsifier,an acrylic film material modified by hydroxyl silicon oil was synthesized by seeding emulsion polymerization technique.Effects of soft to hard monomers ratio,temperature,amounts of emulsifier and polysilicone on the properties of polymerization emulsion were studied.Experimental results show that the stability of polymerization emulsion was higher than others when the optimal mass ratio of soft to hard monomers was set as 13:12,and 3% emulsifiers and 12% polysilicone reacted at 75~80℃.Glass transition temperature(T_g) and water absorption of the film of modified resin are decreased dramatically and the tensile strength is increased.
- seeding emulsion polymerization,
- hydroxyl silicon oil,
- acrylic resin,
- glass transition temperature
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