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Citation: LI Xia, ZHANG Ting-Ting, JU Yan-Ling. Synthesis and Crystal Structure of Nd(Ⅲ) Complex with 2,4-Dimethylbenzooic acid and 2,2'-Bipyridine[J]. Chinese Journal of Applied Chemistry, ;2006, 23(9): 1055-1057. shu

Synthesis and Crystal Structure of Nd(Ⅲ) Complex with 2,4-Dimethylbenzooic acid and 2,2'-Bipyridine

1.
Department of Chemistry, Capital Normal University, Beijing 100037

Corresponding author: LI Xia,
Received Date: 16 October 2005
Available Online: 5 January 2006
Fund Project: 北京市教育委员会科技发展计划面上项目(KM200510028007) (KM200510028007)

Complex {[Nd₂(2,4-DMBA)₆(bipy)₂]5.5H₂O} was synthesized(2,4-DMBA:2,4-dimethylbenzoate;bipy:2,2'-bipyridine).The crystal structure of the complex was determined by the X-ray diffraction method.The complex crystallized in the triclinic system with space group P1,a=1.121 96(15) nm,b=1.236 39(17) nm,c=1.594 5(2) nm,α=69.636(2)°,β=71.641(2)°,γ=83.271(2)°.M=797.45,V=1.960(7) nm³,Z=2,D_calc=1.351 Mg/m³).Two metal ions were bridged by four carboxyl groups of 2,4-dimethylbenzoate,forming a binuclear complex.The coordination number of the metal ion is nine.
- neodymium,
- dimethylbenzoic acid,
- dipyridine,
- crystal structure
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