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Citation: MA Deng-Sheng, HU Bing-Cheng, CAO Biao, LÜ Chun-Xu. Synthesis of [13,17-Bis(-2-methoxycar-bonylethyl)-2,7,12,18-tetramethyl-porphyrinato]-Cu(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;2006, 23(9): 961-964. shu

Synthesis of [13,17-Bis(-2-methoxycar-bonylethyl)-2,7,12,18-tetramethyl-porphyrinato]-Cu(Ⅱ)

1.
The College of Chemical and Chemical Engineering of Nanjing University of Science and Technology, Nanjing 210094

Corresponding author: LÜ Chun-Xu,
Received Date: 23 October 2005
Available Online: 20 January 2006

Deuteroheminchloride(4),3,8-[2,7,12,18-tetramethal-21H,23H-porphyrin-13,17-diyl]-dipropionyloxy-dimethylester(5) and [3,17-bis(-2-methoxy-carbonylethyl)-2,7,12,18-tetramethyl-porphyrinato]-Cu(Ⅱ)(6) were synthesized.The effects of the amount of resorcin on the yield of compound 4 were studied and the results indicated that the best yield could reach to 95.7% at n(resiorcin):n(hemin)=25:1.The effects of the operation modes of extraction on the yield of compound 5 were studied and the results showed that the yield could be improved to 85% in a system of 200 mL of dichloromethane,100 mL of 10%ammnia and 100 mL of water.The effects of the cupric reagents on the yield of compound 6 were also studied and the results showed that the best yield was nearly to 100% when cupric nitrate was used.The structures of compound 5 and compound 6 were confirmed by mp,TCL,IR,MS,and ¹H NMR.
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