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Citation: LI Xian-Cai, CAO Xiao-Hua, XU Chang-Long. Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ Catalyzed by WO₃[J]. Chinese Journal of Applied Chemistry, ;2006, 23(11): 1249-1252. shu

Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ Catalyzed by WO₃

1.
a Department of Chemistry, College of Science, Nanchang University, Nanchang 330047;
2.
b College of Chemistry and Chemical Engineering, Jiujiang University, Jiujiang

Corresponding author: LI Xian-Cai,
Received Date: 15 December 2005
Available Online: 20 April 2006
Fund Project: 江西省自然科学基金(0520037)资助项目 (0520037)

Adipic acid was synthesized by WO₃-catalyzed oxidation of cyclohexanone with 30% hydrogen peroxide in the absence of organic solvent and phase-transfer catalyst.The influence of reaction conditions such as catalyst amount,hydrogen peroxide amount,reaction temperature and time on the oxidation was investigated.Under the optimal conditions,i.e.when n(cyclohexanone):n(hydrogen peroxide):n(tungsten trioxide) was 100:500:2,and the reaction temperature was 120℃,the reaction time was 6 h,the isolated yield of adipic acid could reach 80.3% and its purity was 99.8%.The catalyst could be reused for 5 times and the isolated yield of adipic acid was still above 70.2%.
- adipic acid,
- cyclohexanone,
- tungsten trioxide,
- hydrogen peroxide
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Oxidation of Cyclohexanone to Adipic Acid with 30% H2O2 Catalyzed by WO3

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通讯作者: 陈斌, bchen63@163.com

Oxidation of Cyclohexanone to Adipic Acid with 30% H₂O₂ Catalyzed by WO₃