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Citation: LIU Wei-Min, ZOU Xiao-Mao, WANG Yi-Feng, HU Fang-Zhong, ZHU You-Quan, YANG Hua-Zheng. Synthesis and Herbicidal Activities of Pyrimidiny(thio) ether Derivatives[J]. Chinese Journal of Applied Chemistry, ;2006, 23(11): 1190-1194. shu

Synthesis and Herbicidal Activities of Pyrimidiny(thio) ether Derivatives

1.
Institute of Elemento-Organic Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Corresponding author: YANG Hua-Zheng,
Received Date: 12 December 2005
Available Online: 6 March 2006
Fund Project: 国家重点基础研究发展规划(2003CB114400) (2003CB114400)国家自然科学基金(20372040) (20372040)

In an attempt to find novel herbicidal compounds,a series of pyrimidiny(thio) ether derivatives was synthesized by nucleophilic substitution of the chlorine at the 4-and 2-positions of 2,4-dichloropyrimidine in turn.The structures of the title compounds were confirmed by elemental analysis,¹H NMR and X-ray diffraction methods.The preliminary bioassay results indicate that some of them have herbicidal activity to a certain degree.For example,compounds 7c,7j,7k and 7m exhibit excellent activities against Rape at a dosage of 1×10^-4 g/mL(inhibitory ratio 80%).
- pyrimidiny(thio) ether,
- dimethylamino,
- synthesis,
- herbicidal activity
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