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Citation: JU Yan-Ling, ZHANG Ting-Ting, LI Xia. Synthesis, Crystal Structure and Property of [Dy(4-FBA)₃ 2, 2'-bpy]₂ Complex[J]. Chinese Journal of Applied Chemistry, ;2006, 23(12): 1407-1409. shu

Synthesis, Crystal Structure and Property of [Dy(4-FBA)₃ 2, 2'-bpy]₂ Complex

1.
Department of Chemistry, Capital Normal University, Beijing 100037

Corresponding author: LI Xia,
Received Date: 28 December 2005
Available Online: 6 April 2006
Fund Project: 北京市教育委员会科技发展计划面上资助项目(KM200510028007) (KM200510028007)

The [Dy(4-FBA)₃·2,2'-bpy]₂ complex was synthesized from 4-fluorobenzoic acid(4-HFBA),2,2'-bipyridine(2,2'-bpy) and DyCl₃·6H₂O.The crystal structure of the complex was determined by means of X-ray diffraction method.The complex crystallized into triclinic crystals with P1 symmetry and the unit cell parameters are a=1.041 75(15) nm,b=1.067 30(15) nm,c=1.361 57(19) nm,α=106.030(2)°,β=99.256(2)°,γ=95.949(2)°.M=735.99,V=1.418 5(3) nm³,Z=2,D_calc=1.723 mg/m³,F(000)=722.The two Dy³⁺ ions are bonded to four oxygen atoms from 4-fluorobenzoic acid,forming a binuclear molecule.The coordination number of the metal ion is eight.The complex exhibits photoluminescent emission peaks at 481 nm and 575 nm,corresponding to the transitions of the Dy³⁺ ion:⁴F_9/2→⁶H_15/2 and ⁴F_9/2→⁶H_13/2.
- dysprosium,
- fluorobenzoic acid,
- mixed-ligand complex,
- crystal structure,
- characterization
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Synthesis, Crystal Structure and Property of [Dy(4-FBA)3 2, 2'-bpy]2 Complex

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Synthesis, Crystal Structure and Property of [Dy(4-FBA)₃ 2, 2'-bpy]₂ Complex