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Citation: MA Juan, ZHANG Jun-Song, ZHOU Yao-Ming, LU Tian-Hong, LI Cun. Photocatalytic Performance of Sodium Thioglycolate Modified ZnS Synthesized by Room Temperature Solid Phase Method[J]. Chinese Journal of Applied Chemistry, ;2006, 23(12): 1368-1372. shu

Photocatalytic Performance of Sodium Thioglycolate Modified ZnS Synthesized by Room Temperature Solid Phase Method

MA Juan ^a ,
ZHANG Jun-Song ^a ,
ZHOU Yao-Ming ^a ,
LU Tian-Hong ^a,b ,
LI Cun ^a,,

1.
a College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097;
2.
b Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun

Corresponding author: LI Cun,
Received Date: 7 January 2006
Available Online: 7 April 2006
Fund Project: 江苏省科技厅自然科学基金(BK2003102) (BK2003102)江苏省自然科学基金(2003103SBZB232) (2003103SBZB232)南京师范大学校青年基金(2004103XQNBQ42) (2004103XQNBQ42)

The sodium thioglycollate modified ZnS with an average particle size of 2~4 nm was synthesized via the solid phase reaction method at room temperature using zinc acetate,Na₂S and thioglycollic acid as raw materials.Its composition and structure were characterized by several spectroscopic techniques.It was found that the aggregation of ZnS is prevented because of the presence of sodium thioglycollate,while ensure its uniform dispersion in aqueous solution.The sodium thioglycollate modified ZnS shows high photocatalytic activity for the degredation of methyl orage,which is affected by the pH value of the solution.When the pH of the solution is 3.5,the photocatlytic activity of sodium thioglycollate modified ZnS for the photodegradation of methyl orange can reach as high as 99.4%.
- solid phase reaction method,
- sodium thioglycollate modified ZnS,
- methyl orange,
- photocatalysis
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