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Citation: GU Xiao-Mei, DAI Jie, LI Shu-Hua. Synthesis and Photocatalytic Activity of A Novel ZnS Compound Coordinated with Triethylene Tetramine[J]. Chinese Journal of Applied Chemistry, ;2007, 24(1): 49-52. shu

Synthesis and Photocatalytic Activity of A Novel ZnS Compound Coordinated with Triethylene Tetramine

GU Xiao-Mei ^a,, ,
DAI Jie ^b ,
LI Shu-Hua ^a

1.
a NanTong Textile Vocational Technology College, Nantong 226007;
2.
b Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou

Corresponding author: GU Xiao-Mei,
Received Date: 18 February 2006
Available Online: 6 June 2006
Fund Project: 国家自然科学基金资助项目(2007102) (2007102)

A novel inorganic-organic hybrid polymeric compound[(ZnS)₃(NH₂CH₂CH₂NHCH₂)₂)]_n was synthesized by solvothermal techique from sulfur and zinc(Ⅱ) salt in triethylene tetramine.Detailed characterizations comfirmed the coordination of triethylene tetramine to ZnS moiety and the formation of the new compounds.The structure of the compound was characterized by IR, XRD and TEM.The compound is a stable polymer and has little solubility in water, ethanol, acetone and chloroform.The compound exhibited a considerably good photocatalytic activity in degradation of a dye reactive violet X-2R and kept nearly the same activity after 10 repeated experiments.
- zinc sulfide,
- coordination compound,
- solvothermal synthesis,
- triethylene tetramine,
- photocatalytic activity
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