Citation:
LIU Guo-Hua, YU Han, YAO Mei, FANG Hai-Bin. Synthesis and Plant Growth-Regulating Activity of Ethyl α-[4-(disubstituedbenzylidene) iminophenoxy] propionate[J]. Chinese Journal of Applied Chemistry,
;2007, 24(2): 152-156.
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Eleven ethyl α-[4-(substituedbenzylidene) iminophenoxy]propionates were synthesized through coupling of aromatic aldehydes with ethyl α-(4-aminophenoxyl) propionate.All compounds were characterized by means of 1H NMR,UV,IR and elemental analysis.The effects of substituents of aromatic aldehyde on reaction yields were studied.The results showed that the coupling reaction using 4-nitro-benzaldehyde with electron-withdrawing subtituents gave the highest yield in 93%,while the lowest reaction yield of 54% was obtained using 4-methylbenzaldehye,which has electron-donating substituents.The preliminary biological tests show that most of the compounds possess plant growth-regulating activities at a low concentration(10 ppm). Among those compounds,6b and 6f show the root growth-regulating activities of 52% and 55% for Cucumis Sativa L.,respectively;while compound 6j gives a inhibitory activity of 75% for root of Cucumis Sativa L.. Compound 6b also gives a cell-growing activity of 51% for Triticum aestivum L.and compound 6h gives a stalk growth-regulating activity of 53% for Cucumis Sativa L.
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