Citation:
WANG Hai-Shui, LI Zhong, SONG Gong-Hua, HUANG Qing-Chun, ZHANG Zheng, ZHENG Zhen. Synthesis and Insecticidal Activity of Novel Nitromethylene-containing Compounds[J]. Chinese Journal of Applied Chemistry,
;2007, 24(4): 370-373.
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Neonicotinoid-insecticides are the inhibitors of insect nAChRs with higher herbicidal activity,higher degree of selectivity,and excellent environmental safety.Based on the relationship between structure and activity of nitromethylene heterocycle compounds,and using imidacloprid and its analogues NTN32692 as a model,new compounds which contain the framework of imidacloprid linking cyclohexane were synthesized and characterized with 1H NMR,IR and HR-MS.The bioassay indicates that nine nitromethylene heterocycle compounds have certain insecticidal activities against Aphis craccivora at 500 mg/L and the best one is 73%.
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