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Citation: ZHAO Guo-Xin, DU Chen-Xia, YE Bao-Xian. Synthesis and Electrochemical Characteristics of A New Oxadiazol Derivative with β-Diketonate[J]. Chinese Journal of Applied Chemistry, ;2007, 24(7): 742-746. shu

Synthesis and Electrochemical Characteristics of A New Oxadiazol Derivative with β-Diketonate

1.
Department of Chemistry, Zhengzhou University, Zhengzhou 450052

Corresponding author: YE Bao-Xian,
Received Date: 16 August 2006
Available Online: 2 November 2006
Fund Project: 国家自然科学基金资助项目(20475050) (20475050)

4-(5-Methyl-oxadiazole)-phenyl-1,3 butyl diketonate was synthesized via dehydration reaction of 4-acetyl phenylformic ester and hydrazine hydrate,and characterized by IR and ¹H NMR.UV-Vis spectra and electrochemical characteristics of the compound were investigated.In addition,the energy gap (E_g) was evaluated to be 2.72 eV from the onset absorption wavelength (λ_onset/nm) of the UV-Vis spectra,and the energy levels of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) were calculated by cyclic voltammetry (CV) and UV-Vis spectrometry.The measurement results of the energy levels indicate that the electron affinity of the compound is higher than that of PBD which is the normal electron-transporting material.Thus it could improve the efficiency of the electroluminescent device when it is used as electron transport layer.
- oxadiazole,
- β-diketonate,
- UV-Vis spectra,
- electrochemistry,
- energy levels
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