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Citation: FEI Xue-Ning, YANG Shao-Bin, LIU Li-Juan, SHI Bo-Jie, ZHANG Bao-Lian. Study on Ullmann Condensation Reaction of Bromamine Acid[J]. Chinese Journal of Applied Chemistry, ;2007, 24(10): 1136-1139. shu

Study on Ullmann Condensation Reaction of Bromamine Acid

1.
Department of Material Science and Engineering, Tianjin Institute of Urban Construction, Tianjin 300384

Corresponding author: FEI Xue-Ning,
Received Date: 28 October 2006
Available Online: 8 February 2007
Fund Project: 教育部科学技术重点资助项目(205013) (205013)

The catalytic system of sulfuric acid-water-copper used in Ullmann condensation reaction of bromamine acid was replaced with a strong acid ion exchange resin-ethanol-copper system. The effect of the ion exchange resin loading, the kind of solvent, and the reaction temperature on the yield of the condensation product was investigated. The results show that the yield of the condensation product could reach 94.0% in ethanol-water(9:1) at 70℃ after 3 h. The strong acid ion exchange resin, copper powder and ethanol could be reused under the reaction conditions. The activity of the resin was not obviously reduced after reusing 5 times, and 70%~80% ethanol and 85%~90% copper powder in the reaction can be recovered.
- strong acid ion exchange resins,
- Ullmann condensation,
- amino-bromoanthraquinone-sulfonic sodium,
- C.I pigment red 177 intermediate
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