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Citation: ZHANG Jun-Zhen, YANG Bing-Qin, YANG Ya-Ting, ZHANG Bing-Lin. Synthesis,Characterization and Crystal Structure of 1-Ferrocenesulfonyl-2-long Carbon Chain Alkyl Benzimidazole[J]. Chinese Journal of Applied Chemistry, ;2007, 24(11): 1273-1278. shu

Synthesis,Characterization and Crystal Structure of 1-Ferrocenesulfonyl-2-long Carbon Chain Alkyl Benzimidazole

1.
Department of Chemistry, Northwest University, Xi'an 710069

Corresponding author: YANG Bing-Qin,
Received Date: 30 December 2006
Available Online: 6 April 2007
Fund Project: 国家自然科学基金(20572085) (20572085)陕西省自然科学基金(2005B20)资助项目 (2005B20)

Six new 1-ferrocenesulfonyl-2-benzimidazole derivatives were prepared from the reaction of ferrocenesulfonylchloride with benzimidazole derivatives in the presence of dichloromethane and n-tetrabutylammonia chloride. The yields of six new ferrocenesulfonyl benzimidazole derivatives were about 80%. The structures were confirmed by IR, ¹H NMR, elemental analysis and MS. Its crystal structure was determined via X-ray single crystal diffraction. The title compound a₂ belongs to the monoclinic system with space group C2/c, and the unit cell parameters are a=2.825 2(2) nm, b=0.976 96(7) nm, c=1.648 28(12) nm, α=90°, β=92.053(2)°, γ=90°, V=4.546 6(6) nm³, Z=8, F(000)=2 024, M_r=481.40, D_c=1.407 g/cm³, μ=0.784 mm^-3, R₁=0.049 5, wR₂=0.151 7. The results show that the reactions of 2-alkylbenzimidazoles with ferrocenesulfonyl chloride give 1-ferrocenesulfonyl-2-alkylbenzimidazoles in good yields.
- ferrocenesulfonyl benzimidazole,
- synthesis,
- characteristic,
- crystal structure
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