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Citation: HE Xiao-Li, LIN Sen, GUO Xuan, LU Lu-De, WANG Xin, YANG Xu-Jie. Synthesis and Catalytic Properties of Tetraorganodistannoxanes Containing Silicon[J]. Chinese Journal of Applied Chemistry, ;2007, 24(11): 1268-1272. shu

Synthesis and Catalytic Properties of Tetraorganodistannoxanes Containing Silicon

HE Xiao-Li ^a,b ,
LIN Sen ^b,, ,
GUO Xuan ^b ,
LU Lu-De ^a ,
WANG Xin ^a ,
YANG Xu-Jie ^a

1.
a School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing;
2.
b Department of Chemistry, Nanchang University, Nanchang 330047

Corresponding author: LIN Sen,
Received Date: 3 December 2006
Available Online: 24 February 2007
Fund Project: 江西省自然科学基金资助项目(0520064) (0520064)

Three tetraorganodistannoxanes containing silicon were synthesized and their catalytic properties in esterification and acetalization were observed via the reactions of acetic acid with isoamyl alcohol and butyraldehyde with glycol. The factors affecting the reaction, such as the catalyst dosage, reaction time and solvent kind, etc. were discussed. The results show that three tetraorganodistannoxanes displayed similar good catalytic activities compared to dichlorotetrabutyldistannoxane in the esterification and acetalization. When the dosage of [ClBu₂SnOSn(CH₂SiMe₃)₂Cl]₂ was 1.5% based on the mass of the reactant, the yield of isoamyl acetate was 91.8%, and the yield of butyraldehyde glycol acetal 94.2%. The different alkyl and bridging groups on Sn sites in the structure of the tetraorganodistannoxanes showed influences, to a certain extent, on the catalytic activities of these compounds.
- tetraorganodistannoxane containing silicon,
- synthesis,
- catalysis,
- esterification,
- acetalization
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