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Citation: ZHANG Ying-Qun, WANG Chun, MA Jing-Jun, LI Jing-Ci, TANG Ran-Xiao, WANG Yan-Ping. Condensation of Thiazolidineone Derivatives with Aromatic Aldehydes in Water[J]. Chinese Journal of Applied Chemistry, ;2008, 25(1): 122-124. shu

Condensation of Thiazolidineone Derivatives with Aromatic Aldehydes in Water

1.
College of Science, Agricultural University of Hebei, Baoding 071001

Corresponding author: ZHANG Ying-Qun,
Received Date: 8 January 2007
Available Online: 30 April 2007
Fund Project: 河北省教育厅计划项目(20040015) (20040015)河北农业大学非生命学科和新兴学科科研发展基金资助项目(2005012) (2005012)

A series of 5-arylidene thiazolidineone derivatives was synthesized by condensation reaction of aromatic aldehydes with thiazolidineone derivatives in the presence of NaAc and Bu₄NBr in water.The reaction was carried out at 95℃ for 2~8 h,the yields of the products were ranged in 65.3%~91.3%,which were higher or similar to those in organic solvent.The results indicate that the cycles of thiazolidineone derivatives may be opened under the action of a strong base,such as NaOH.NaAc is an efficient catalyst for the condensation reaction and could be recycled.The mothod is manipulatively simple and environmental friendly.The products were identified by ¹H NMR and IR spectra.
- aqueous media,
- aromatic aldehyde,
- thiazolidinedione,
- N-phenylrhodanine,
- tetrabutylaminebromide
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