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Citation: ZHOU Jie, DU Bin, ZHANG Zhen-Zhong. Separation of Mono-6-N-Allylamino-perphenylcarbamoylated β-Cyclodextrin with Silica Gel[J]. Chinese Journal of Applied Chemistry, ;2008, 25(5): 548-551. shu

Separation of Mono-6-N-Allylamino-perphenylcarbamoylated β-Cyclodextrin with Silica Gel

1.
The school of Pharmacy, Zhengzhou University, Zhengzhou 450001

Corresponding author: ZHOU Jie,
Received Date: 1 July 2007
Available Online: 26 September 2007
Fund Project: 教育部高等学校博士学科点专项科研基金(20040335045)资助项目 (20040335045)

With the column of 0.07~0.05 mm silica gel,the separation of perphenylcarbamoylated β-cyclodextrin was investigated.The effects of mobile phase composition,bed volume,sample load,flow rate and column temperature on separation were studied systematically.The mixture was separated and the optimal conditions were obtained.The best technological conditions are approached:the bed height is 32 cm;the mobile phase is V(hexane):V(ethyl acetate)=2:1;the flow rate is 0.6 mL/min;the column temperature is 30℃;and the maximal sample load is 0.02 g.With these conditions,the recovery was 40.91% of first eluent and 50% of last eluent,respectively.
- cyclodextrin derivative,
- column of silica gel,
- separation,
- preparation,
- optimize
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