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Citation: XU Qi-Jie, LIU Ju-Sheng, LIU Fei, CUI Yuan-Chen. Catalytic Properties of Complexes of Cross-linking Humic Acid Supported Metals on Heck Reaction[J]. Chinese Journal of Applied Chemistry, ;2008, 25(8): 926-930. shu

Catalytic Properties of Complexes of Cross-linking Humic Acid Supported Metals on Heck Reaction

1.
a College of Chemistry & Chemical Engineering, Henan University, Kaifeng 475001;
2.
b Department of Chemistry, Zhengzhou University, Zhengzhou

Corresponding author: CUI Yuan-Chen,
Received Date: 6 August 2007
Available Online: 30 December 2007
Fund Project: 河南省自然科学基金项目(611020500) (611020500)

Cross-linking humic acid(CL-HA) was synthesized readily with epichlorohydrine as cross-linking reagent. The product was analyzed and confirmed by IR spectrum and solvent experiment. The catalysts of CL-HA-Pd and CL-HA-Pd/Ni were prepared via supporting PdCl₂ and NiCl₂ on cross-linking humic acid, respectively. The two catalysts were reduced with NaBH₄. The catalytic performances of the four catalysts, CL-HA-Pd, CL-HA-Pd/Ni and their reducing products were studied via the Heck reaction of aryl halide with vinyl compounds. The results show that the catalyst could catalyze the Heck reaction of substituted aryl halide with crylic acid, the yields were above 80%.
- cross-linking humic acid,
- palladium,
- nickel,
- NaBH₄,
- Heck reaction
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