Home

Citation: HE Wen-Wei, LIAO Wu-Ping, NIU Chun-Ji, LI De-Qian. Determination of Some Basic Constants of P-tert-butylcalixarene Acetic Acid via Two-phase Titration Method[J]. Chinese Journal of Applied Chemistry, ;2008, 25(8): 877-881. shu

Determination of Some Basic Constants of P-tert-butylcalixarene Acetic Acid via Two-phase Titration Method

1.
a State Key Laboratory of Application of Rare Earth Resources, Changchun Institute of Applied Chemistry, Changchun 130022;
2.
b Graduate School of Chinese Academy of Sciences, Beijing

Corresponding author: LI De-Qian,
Received Date: 20 August 2007
Available Online: 11 October 2007
Fund Project: 国家自然科学基金(20371046,50574080) (20371046,50574080)国家"八六三"(2002AA647070)资助项目 (2002AA647070)

Some basic constants of p-tert-butylcalixarene acetic acid ^tBu[4]CH₂COOH and ^tBu[6]CH₂COOH including solubility(S) in water, dissociation constant(K_a) in aqueous solution, dimerization constant(K₂) and distribution constant(K_D) between water and chloroform were determined at 25℃ by two-phase titration method. The results are as follows: ^tBu[4]CH₂COOH: S₄=(2.03±0.04)×10^-4 mol/L, K_a,4=(1.50±0.02)×10^-5, K_D,4=1.55×10² and K_2,4=3.73×10². ^tBu[6]CH₂COOH: S₆=(1.25±0.05)×10^-4 mol/L, K_a,4=(8.71±0.05)×10^-6, K_D,6=1.28×10² and K_2,6=3.88×10².
- calixarene,
- two-phase titration,
- constants,
- determination
1. [1]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
2. [2]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
3. [3]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
4. [4]
  Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
5. [5]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103
6. [6]
  Shuyong Zhang , Yaxian Zhu , Wenqing Zhang , Yuzhi Wang , Jing Lu . Ideological and Political Design of Combustion Heat Measurement Experiment: Determination of Heat Value of Agricultural and Forestry Wastes. University Chemistry, 2024, 39(2): 1-6. doi: 10.3866/PKU.DXHX202303026
7. [7]
  Jiarui Wu , Gengxin Wu , Yan Wang , Yingwei Yang . Crystal Engineering Based on Leaning Towerarenes. University Chemistry, 2024, 39(3): 58-62. doi: 10.3866/PKU.DXHX202304014
8. [8]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
9. [9]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
10. [10]
  Xiaoyan Wang , Chao Wang , Dongmei Dai , Yanling Geng , Hongtao Gao . Design of Ideological and Political Education for the Experiment on Calcium Content Determination in Calcium Supplements. University Chemistry, 2024, 39(2): 162-167. doi: 10.3866/PKU.DXHX202307074
11. [11]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
12. [12]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
13. [13]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
14. [14]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
15. [15]
  Zhongbin Pan , Shijie Huang , Yunjie Luo , Hongzhen Xie . Design of a Comprehensive Experiment for Determining Permanganate Index (COD_Mn) in Drinking Water. University Chemistry, 2024, 39(7): 354-360. doi: 10.12461/PKU.DXHX202311040
16. [16]
  Jiangjuan Shao , Xuan Li , Jingdan Weng , Xiaolei Chen , Fei Xu , Yulu Ma , Nianguang Li , Shizhong Zheng . Improvement in the Experimental Teaching Design of Physical and Chemical Identification and Quantification of Mineral Drugs. University Chemistry, 2024, 39(10): 137-142. doi: 10.3866/PKU.DXHX202312079
17. [17]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
18. [18]
  Lisen Sun , Yongmei Hao , Zhen Huang , Yongmei Liu . Experimental Teaching Design for Viscosity Measurement Serves the Optimization of Operating Conditions for Kitchen Waste Treatment Equipment. University Chemistry, 2024, 39(2): 52-56. doi: 10.3866/PKU.DXHX202307063
19. [19]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
20. [20]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(350)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return