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Citation: JIANG Yan, ZHANG Chun-Xian, SUN Xiao-Qiang, XI Hai-Tao, MENG Qi, WANG Xin. Synthesis of A Novel Chiral Polydentate Ligand[J]. Chinese Journal of Applied Chemistry, ;2008, 25(9): 1122-1124. shu

Synthesis of A Novel Chiral Polydentate Ligand

JIANG Yan ^a,b ,
ZHANG Chun-Xian ^b ,
SUN Xiao-Qiang ^b,, ,
XI Hai-Tao ^b ,
MENG Qi ^b ,
WANG Xin ^a

1.
a Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210049;
2.
b Jiangsu Provincial Key Laboratory of Fine Petrochemical Engineering, Jiangsu Polytechnic University, Changzhou 213164

Corresponding author: SUN Xiao-Qiang,
Received Date: 28 October 2007
Available Online: 3 March 2008

A novel chiral polydentate ligand(1R,2R)-1,2-diphenyl-2-(2-methoxyethoxy)-ethoxyethyl picolinic acid ester was synthesized from trans-1,2-stilbene,tert-butyldimethylsilyl chloride and 1-(2-methoxy)-2-bromoethane through functional group protection,etherification,deprotction and substitution.The structure of the target product was characterized by NMR and LCMS and elemental analysis.
- trans-stilbene,
- tert-butyldimethylsilyl,
- (R,R)-hydrobenzoin,
- chiral polydentate ligand
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