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Citation: ZHANG Jing-Jinga, HUANG Wu, YI Qing-Feng, ZHOU Wei, LI Xiao-Hu, LIU Xiao-Ping. Synthesis of Adipic Acid by Electro-oxidation of Cyclohexanol[J]. Chinese Journal of Applied Chemistry, ;2008, 25(10): 1171-1175. shu

Synthesis of Adipic Acid by Electro-oxidation of Cyclohexanol

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a College of Chemistry, Zhanjiang Normal College, Zhanjiang 524048;
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b School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201

Corresponding author: YI Qing-Feng,
Received Date: 21 September 2007
Available Online: 1 March 2008
Fund Project: 湖南省教育厅重点项目(07A019) (07A019)教育部留学回国人员科研启动基金([2007]1108)资助项目 ([2007]1108)

Electro-synthesis of adipic acid from cyclohexanol in alkaline solution was investigated.Before electrolysis,the Ni electrode was activated by voltammetric technique to form NiOOH on its surface.Cyclo-hexanol was first oxidized to cyclohexanone and then to adipic acid on the activated Ni electrode.Orthogonal tests showed that the maximum yield of adipic acid was 42.59% under the optimum conditions of current density of 6×10^-3 A/cm²,reaction temperature of 60℃,reaction time of 16 F/mol,and c(NaOH)=1.0 mol/L.Results of the kinetic study on the cyclohexanol oxidation show that the reaction obeys the consecutive reaction mechanism,and the formation of cyclohexanone is a fast step and the formation of adipic acid is a slower and rate-determining step.The corresponding kinetic equations of cycylohexanol oxidation were derived.The proposed kinetic model gave a satisfactory description for the electro-oxidation of cyclohe-xanol in 1 mol/L NaOH.
- cyclohexanol,
- nickel electrode,
- electro-oxidation,
- cyclohexanone,
- adipic acid
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