Citation: WANG Miao, SHEN Xin-Lin, TANG Yan-Feng, JIANG Guo-Qing, SHI Yu-Jun. Glycine-Assisted Hydrothermal Synthesis of CaF2∶Ln3+(Ln=Eu, Tb) Microcrystals with Different Morphologies[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2660-2666.
-
By employing KBF4 or K2SiF6 as fluoride source, a facile glycine-assisted hydrothermal route has been developed to synthesize a series of well-dispersed CaF2∶Ln3+(Ln=Eu, Tb) microcrystals with a variety of morphologies, such as cubes, hollow polyhedra and hollow spheres. X-ray diffraction (XRD), Fourier transform IR (FTIR), scanning electron microscopy (SEM) and photoluminescence (PL) were used to characterize the purity, crystalline phase, morphologies and the photoluminescence properties of the samples. The XRD results show that all the as-prepared CaF2 have cubic structure and high crystallinity. The SEM results indicate that, in the presence of glycine, the as-prepared CaF2 microcrystals present morphologies of highly dispersed hollow polyhedra and hollow spheres obtained from KBF4 and K2SiF6, respectively. Meanwhile, the CaF2 hollow spheres were assembled from numerous nanocubes. In the synthetic process, glycine, fluoride source and reaction time play crucial role in confining the growth of the different morphological CaF2 microcrystals. The growth mechanism for products with diverse microstructures have been proposed based on the experimental results.
-
-
[1]
[1] Nakajima T, Zemva B, Tressaud A. Advanced Inorganic Fluorides. Amsterdam: Elsevier, 2000.
-
[2]
[2] Kinsman B E, Hanney R. Adv. Mater. Opt. Electron., 1995,5:109-115
-
[3]
[3] Moon H J, Kim K N, Kim K M, et al. J. Biomed. Mater. Res. Part A, 2005,74A:497-502
-
[4]
[4] Feldmann C, Roming M, Trampert K. Small, 2006,2:1248-1250
-
[5]
[5] Sun X M, Li Y D. Chem. Commun., 2003:1768-1769
-
[6]
[6] Zhang C M, Li C X, Peng C, et al. Chem. Eur. J., 2010,16: 5672-5680
-
[7]
[7] Zhang X M, Quan Z W, Yang J, et al. Nanotechnology, 2008,19:075603(8pp)
-
[8]
[8] Hou S Y, Zou Y C, Liu X C, et al. CrystEngComm, 2011,13:835-840
-
[9]
[9] Quan Z W, Yang D M, Yang P P, et al. Inorg. Chem., 2008,47:9509-9517
-
[10]
[10] Du Y P, Sun X, Zhang Y W, et al. Cryst. Growth Des., 2009,9:2013-2019
-
[11]
[11] Mao Y B, Zhang F, Wong S S. Adv. Mater., 2006,18:1895-1899
-
[12]
[12] Wang W S, Zhen L, Xu C Y, et al. ACS Appl. Mater. Interfaces, 2009,1:780-788
-
[13]
[13] Guo F Q, Zhang Z F, Li H F, et al. Chem. Commun., 2010, 46:8237-8239
-
[14]
[14] WANG Miao(王淼), CHEN Ting-Ting(陈婷婷), TANG Yan-Feng(汤艳峰), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:185-190
-
[15]
[15] Yang X F, Dong X T, Wang J X, et al. J. Alloy Compd., 2009,487:298-303
-
[16]
[16] Yang X F, Dong X T, Wang J X, et al. Mater. Lett., 2009, 63:629-631
-
[17]
[17] Chen H M, Zhao Y Q, He J H, et al. Analytica Chimica Acta, 2010,659:266-273
-
[18]
[18] Wang M, Shi Y J, Jiang G Q. Mater. Res. Bull., 2012,47: 18-23
-
[19]
[19] CHEN Guang-De(陈广德), XU Zhen-Mei(徐贞梅). Fine Chem.(Jingxi Huagong), 2002,19:701-702,726
-
[20]
[20] ZHANG Da-Fei(张大飞), ZHAO Ri-Getu(照日格图), LIU Jian-Hua(刘建华), et al. Chinese J. Spect. Lab.(Guangpu Shiyanshi), 2006,23:91-95
-
[21]
[21] CAO Xiao-Feng(曹霄峰), ZHANG Lei(张雷), MA Ying-Li (马英丽),et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26:787-792
-
[22]
[22] Qian H S, Yu S H, Gong J Y, et al. Cryst. Growth Des. 2005,5:935-939
-
[23]
[23] WANG Miao(王淼), SHI Yu-Jun(石玉军), JIANG Guo-Qing (江国庆). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:1785-1790
-
[24]
[24] Wei Z G, Sun L D, Jiang X C, et al. Chem. Mater., 2003,15: 3011-3017
-
[25]
[25] Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004,108: 3387-3390
-
[1]
-
-
[1]
Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
-
[2]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[3]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[4]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[5]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[6]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[7]
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
-
[8]
Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
-
[9]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[10]
Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
-
[11]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[12]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[13]
Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
-
[14]
Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
-
[15]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[16]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[17]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[18]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[19]
Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
-
[20]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(266)
- HTML views(20)