Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2655-2659. shu

Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetatic Acid

1.
1. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;

Corresponding author: GAO Zhu-Qing, GU Jin-Zhong,
Received Date: 1 December 2012
Available Online: 3 June 2012
Fund Project:

A coordination polymer, namely [Cd(3-CPOA)(phen)]_n (1) has been constructed hydrothermally using 3-H₂CPOA (3-H₂CPOA=3-carboxyphenoxyacetatic acid), phen (phen=1,10-phenanthroline) and Cd(OAc)₂·2H₂O. The complex crystallizes in the monoclinic system, space group C2 with a=1.575 3(7) nm, b=1.035 4(5) nm, c=1.133 9(5) nm, β=97.806(4)°, V=1.832 3(15) nm³, D_c=1.764 g·cm^-3, Z=4, R=0.020 4 and wR=0.039 7 (I>2σ(I)). Two Cd(Ⅱ) atoms, two CPOA^2- ligands and two phen ligands form a [Cd₂(CPOA)₂(phen)₂] ring. The rings are connected by the coordination interactions of CPOA^2- ligands and Cd(Ⅱ) ions to generate a 1D double-chain, which are further extended into a 3D metal-organic supramolecular framework by C-H…O hydrogen bond interactions. Luminescent studies show that complex 1 displays strong blue emission at room temperature. CCDC: 853932.
- coordination polymer;cadmium(Ⅱ) complex;hydrogen bond;luminescent properties
1. [1]
  [1] Li L N, Luo J H, Wang S Y, et al. Cryst. Growth Des., 2011, 11:3744-3747
2. [2]
  [2] Song Y S, Yan B, Chen Z X. Inorg. Chem. Commun., 2005, 8:1165-1168
3. [3]
  [3] Wang H L, Zhang D P, Sun D F, et al. Cryst. Growth Des., 2009,9:5273-5282
4. [4]
  [4] Corma A, Iglesias M, Xamena F X L, et al. Chem. Eur. J., 2010,16:9789-9795
5. [5]
  [5] Jiang G Y, Wu T, Zheng S T, et al. Cryst. Growth Des., 2011,11:3713-3716
6. [6]
  [6] GU Jin-Zhong(顾金忠), GAO Zhu-Qing(高竹青), DOU Wei (窦伟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(9):1663-1667
7. [7]
  [7] Li J G, Zang S Q, Tian Z F, et al. CrystEngComm, 2007,9: 915-921
8. [8]
  [8] Chu Q, Su Z, Fan J, et al. Cryst. Growth Des., 2011,11:3885-3894
9. [9]
  [9] Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010,49: 3776-3788
10. [10]
  [10] Wang H L, Zhang D P, Sun D F, et al. CrystEngComm, 2010,12:1096-1102
11. [11]
  [11] Chen S C, Zhang Z H, Zhou Y S, et al. Cryst. Growth Des., 2011,11:4190-4197
12. [12]
  [12] Schnobrich J K, Lebel O, Cychosz K A, et al. J. Am. Chem. Soc., 2010,132:13941-13948
13. [13]
  [13] Xu C Y, Li L K, Wang Y P, et al. Cryst. Growth Des., 2011, 11:4667-4675
14. [14]
  [14] Gu J Z, Lü D Y, Gao Z Q, et al. J. Solid State Chem., 2011, 184:675-683
15. [15]
  [15] NIE Xue(聂雪), QU Jing-Nian(屈景年), CHEN Man-Sheng (陈满生). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(11):2267-2270
16. [16]
  [16] Cao X Y, Li Z J, Zhang J, et al. CrystEngComm, 2008,10: 1345-1349
17. [17]
  [17] Deng Z P, Huo L H, Gao S, et al. Z. Anorg. Allg. Chem., 2010,636:835-839
18. [18]
  [18] GAO Shan(高山), GU Chang-Sheng(谷长生), ZHAO Hui(赵辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(12):1437-1440
19. [19]
  [19] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of G?öttingen, Germany, 1997.
20. [20]
  [20] Li C, Li J, Sun Z G, et al. Inorg. Chem. Commun., 2011,14: 1715-1718
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
6. [6]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
7. [7]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
12. [12]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
13. [13]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
16. [16]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
17. [17]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
18. [18]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
19. [19]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
20. [20]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(179)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142