Citation: FU Feng, GUO Hai-Kang, TANG Long, WU Ya-Pan, HOU Xiang-Yang, REN Yi-Xia. Synthesis, Crystal Structure and Properties of Manganese(Ⅱ) Compound with Azobenzen-4,4′-dicarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2638-2642. shu

Synthesis, Crystal Structure and Properties of Manganese(Ⅱ) Compound with Azobenzen-4,4′-dicarboxylic Acid Ligand

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: FU Feng,
Received Date: 25 June 2012
Available Online: 15 September 2012
Fund Project: 国家自然科学基金(No.21003103) (No.21003103)陕西省教育厅基金(No.2010JS061)资助项目. (No.2010JS061)

A coordination complex [Mn(ADB)(phen)(H₂O)₂] (1) (ADB=azobenzen-4,4′-dicarboxylic acid ion, phen=1,10-phenanthroline) have been synthesized by hydrothermal reaction and characterized by elemental analysis, IR spectra, thermal analysis and electrochemical property, and the crystal structures were determined by single crystal X ray diffraction. Single-crystal X ray diffraction analyses indicate that complex belongs to triclinic system and the space group is P1, the parameters of the crystal cell for the complex are a=0.762 00(13) nm, b=0.915 30(15) nm, c=1.826 2(2) nm, α=88.467(3)°, β=84.145(2)°, γ=77.542(2)°. The manganese centre is six-coordinated, with a distorted octahedral geometry. The Mn(Ⅱ) center is connected to form a 1D zigzag chain structure bridged by azobenzen-4,4′-dicarboxylic acid ligand, further extended into a 3D supramolecular structure through π-π stacking and hydrogen bonding interactions. Magnetic property of 1 is investigated and exhibited antiferromagnetic interactions. CCDC: 847696.
- manganese complex;azobenzen-4,4′-dicarboxylic acid;crystal structure;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142