Citation: NIE Xiang, GUO Xiao-Dong, ZHONG Ben-He, LIU Heng, FANG Wei-Mao. Effect of Mn Source on 5 V LiNi0.5Mn1.5O4 Positive Electrode Materials Prepared by Combustion Method[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2573-2580.
-
Sub-micrometric LiNi0.5Mn1.5O4 cathode materials were prepared by sucrose combustion method with two different Mn sources. The effect of manganese acetate and manganese nitrate on the crystal structure, morphology, particle size and electrical performance of the prepared samples was evaluated by X-ray diffraction (XRD),scanning electron microscopy (SEM), particle size analysis, cyclic voltammetry (CV),galvanostatic charge-discharge test and electrochemical impedance spectroscopy (EIS). XRD analysis shows that the structure of both samples is a typical cubic spinel with Fd3m space group. The particle size and the distribution of the LiNi0.5Mn1.5O4 powder are strongly influenced by Mn source. The materials prepared by manganese acetate have smaller particle size and narrower particle size distribution, which can facilitate Li ions extraction and insertion. Furthermore, the sample LiNi0.5Mn1.5O4 prepared by manganese acetate has better electrochemical performances. An initial specific capacity of 144.5 mAh·g-1 at 1C in the voltage range of 3.6~5.2 V, 96% of the initial capacity after 100 cycles is maintained, and capacities of 136.3, 132.0, 124.7 and 96.6 mAh·g-1 are achieved at the rate of 3C, 5C, 10C and 20C, respectively.
-
-
[1]
[1] Guo X D, Zhong B H, Liu H, et al. J. Electrochem. Soc., 2009,156:A787-A790
-
[2]
[2] TANG Yan(唐艳), ZHONG Ben-He(钟本和), GUO Xiao-Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(4):869-874
-
[3]
[3] Wolfgang M, Jean-Francios C, Dietrich G, et al. Electrochimica Acta, 2010,55:4964-4969
-
[4]
[4] Liu G Q, Wen L, Liu Y M. J. Solid State Electrochem., 2010,14:2191-2202
-
[5]
[5] Chi L H, Dinh N N, Brutti S, et al. Electrochimica Acta., 2010,55:5110-5116
-
[6]
[6] Yi T F, Zhu Y R, Zhu R S. Solid State Ionics., 2008,179: 2132-2136
-
[7]
[7] Mohamed A, Jose M A, Rosa M, et al. J. Power Sources, 2008,185:501-511
-
[8]
[8] CHEN Zhao-Yong(陈召勇), XIAO Jing(肖劲), ZHU Hua-Li (朱华丽), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(9):1417-1421
-
[9]
[9] Yang T Y, Sun K, Lei Z Y, et al. J. Alloys Compd., 2010, 502:215-219
-
[10]
[10] Liu H Y, Wu Y P, Rahm E, et al. J. Solid State Electrochem., 2004,8:450-466
-
[11]
[11] Chang Z R, Dai D M, Tang H W, et al. Electrochimica Acta, 2010,55:5506-5510
-
[12]
[12] DAI Ke-Hua(代克化), MAO Jing(毛景), ZHAI Yu-Chun (翟玉春). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(8):2130-2134
-
[13]
[13] HE Ze-Qiang(何则强), XIONG Li-Zhi(熊利芝), WU Xian-Ming(吴显明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(5): 875-878
-
[14]
[14] Yang T Y, Sun K N, Lei Z Y, et al. J. Solid State Electrochem., 2011,15:391-397
-
[15]
[15] Feng X Y, Shen C, Fang X, et al. J. Alloys Compd.,2011, 509:3623-3626
-
[16]
[16] PANG Pei-Pei(庞佩佩), TANG Zhi-Yuan(唐致远), YUAN Xiu-Lan(袁秀兰). J. Chinese Battery Industry.(Dianchi Gongye),2010,15(3):160-164
-
[17]
[17] Fang X, Ding N, Feng X Y, et al. Electrocheimica Acta, 2009,54:7471-7475
-
[18]
[18] Yi T F, Shu J, Zhu Y R, et al. J. Phys. Chem. Solids, 2009,70:153-158
-
[1]
-
-
[1]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[2]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[3]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[4]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[5]
Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
-
[6]
Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi0.90Co0.06Mn0.04O2 electrode by uniform Li3PO4 coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
-
[7]
Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na3.5V1.5Mn0.5(PO4)3@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
-
[8]
Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO2 by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
-
[9]
Gregorio F. Ortiz . Some facets of the Mg/Na3VCr0.5Fe0.5(PO4)3 battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
-
[10]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[11]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[12]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[13]
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
-
[14]
Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
-
[15]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[16]
Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
-
[17]
Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
-
[18]
Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H2O and Its Intermediates on Electron-Deficient Mn(3+δ)+ for Efficient Photocatalytic H2O2 Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
-
[19]
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
-
[20]
Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(202)
- HTML views(22)