Citation: ZHAI Bin, YI Yong-Ling, HAN Nan-Nan, ZHANG Xiang-Fei. Synthesis, Crystal Structure and Magnetic Research of 1D Chain Manganese Coordination Polymer Based on Pyrazine-2,3,5,6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2535-2539. shu

Synthesis, Crystal Structure and Magnetic Research of 1D Chain Manganese Coordination Polymer Based on Pyrazine-2,3,5,6-tetracarboxylic Acid

1.
1. College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, Henan 476000, China;

Corresponding author: ZHAI Bin,
Received Date: 16 February 2012
Available Online: 12 July 2012
Fund Project: 国家自然科学基金(No.21001071) (No.21001071)河南省教育厅自然科学研究计划(No.2010A150018)资助项目. (No.2010A150018)

Coordination polymer {[Mn₂(phen)₂(H₂pztc)Mn₂(phen)₂(Hpztc)₂ (H₂O)₂]·4H₂O}_n (1) has been synthesized by the hydrothermal reaction of MnCl₂·4H₂O, pyrazine-2,3,5,6-tetracarboxylic acid (H₄pztc) and 1,10-phenanthroline (phen), which were further characterized by IR, elemental analysis, X-ray diffraction single-crystal structural analysis and magnetic susceptibility. It belongs to triclinic crystal system, P1 space group with a=0.955 02(19) nm, b=1.323 4(3) nm, c=1.515 7(3) nm, α=68.95(3)°, β=77.33(3)°, γ=81.92(3)°, V=1.740 3(6) nm³, Z=2. The manganese(Ⅱ) ions in the complex are 6-coordinated and 7-coordinated. The Mn(Ⅱ) ions of complex 1 are connected by pztc and phen, resulting in a 1D chain. Variable temperature magnetic susceptibility measurements reveal the existence of antiferromagnetic interactions in the complex 1. CCDC: 694108.
- one-dimensional chain;manganese(Ⅱ) complex;crystal structure;pyrazine-2,3,5,6-tetracarboxylic acid;magnetic property
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