Citation: CAO Cheng, WEI Tai-Bao, ZHANG Qin-Sheng, LU Yan-Yun, ZHANG You-Ming. Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)oxamethyl]methane Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2530-2534. shu

Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)oxamethyl]methane Acid

1.
1. Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Northwest Normal University, Lanzhou 730070, China;

Corresponding author: ZHANG You-Ming,
Received Date: 16 February 2012
Available Online: 13 July 2012
Fund Project: 国家自然科学基金(No.21064006) (No.21064006) 甘肃省自然科学基金(No.1010RJZA018)资助项目. (No.1010RJZA018)

A semi-rigid tetrahedral linker tetrakis[3-(carboxyphenyl)oxamethyl]methane acid (H₄L) and its coordination polymer [Cu(H₂L)(Py)₂]_n (Py=pyridyne) were synthesized and characterized by elemental analyses, IR spectroscopy, etc. The single crystal structure show the title complex crystallizes in the monoclinic system with space group C2/c, a=1.943 0(7) nm, b=0.926 4(3) nm, c=2.784 9(9) nm, β=96.763(3)°, V=4.978(3) nm³, Z=4, F(000)=1 724. In the complex each Cu(Ⅱ) atoms is coordinated with two pyridyne and two oxygen atom from two arms of H₂L^2-, and displays a one-dimensional line topology with the other two arms free. Platon calculation show that the guest accessible volume (1.397 nm³ per unit cell) comprises 28.1% of the unit cell volume. The thermal analysis shows the title compound is trable up to 236.9 ℃. CCDC: 817405.
- tetrakis[3-(carboxyphenyl)oxamethyl]methane acid;coordination polymer;crystal structure
1. [1]
  [1] Rowsell J L C, Spencer E C, Eckert J, et al. Science, 2005, 309:1350-1354
2. [2]
  [2] Choi H S, Suh M P. Angew. Chem.-Int. Edit., 2009,48:6865-6869
3. [3]
  [3] Shekhah O, Liu J, Fischer R A, et al. Chem. Soc. Rev., 2011,40:1081-1106
4. [4]
  [4] Grunker R, Senkovska I, Biedermann R, et al. Chem. Commun., 2011,47:490-492
5. [5]
  [5] Tanaka D, Henke A, Albrecht K, et al. Nature Chem., 2010, 2:410-416
6. [6]
  [6] Furukawa H, Ko N, Go Y B, et al. Science, 2010,329:424-428
7. [7]
  [7] Guo Z, Cao R, Wang X, et al. J. Am. Chem. Soc., 2009, 131:6894-6895
8. [8]
  [8] Bai H Y, Ma J F, Yang J, et al. Cryst. Growth Des., 2009, 10:995-1016
9. [9]
  [9] Thallapally P K, Tian J, Radha K M, et al. J. Am. Chem. Soc., 2008,130:16842-16843
10. [10]
  [10] Ren S B, Zhou L, Zhang J, et al. Cryst. Eng. Comm., 2010, 12:1635-1638
11. [11]
  [11] Neogi S, Bharadwaj P K. Cryst. Growth Des., 2006,6:433-438
12. [12]
  [12] Kim J, Chen B, Reineke T M, et al. J. Am. Chem. Soc., 2001,123:8239-8247
13. [13]
  [13] Zhang Y M, Pang H X, Cao C, et al. J. Coord. Chem., 2008, 61:1663-1670
14. [14]
  [14] Zhang Y M, Lin Q, Wei T B, et al. Chem. Commun., 2009, 40:6074-6076
15. [15]
  [15] Wei T B, Wang J, Zhang Y M. Sci. China Ser. B: Chem., 2008,51:1051-1056
16. [16]
  [16] Zhang Y M, Yang L Z, Lin Q, et al. Transition Met. Chem., 2005,30:944-947
17. [17]
  [17] Zhang Y M, Lin Q, Wei T B, et al. Inorg. Chim. Acta, 2005, 358:4423-4430
18. [18]
  [18] Laliberté D, Maris T, Wuest J D. J. Org. Chem., 2004,69: 1776-1787
19. [19]
  [19] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.
20. [20]
  [20] Jeffrey G A, Maluszynska H, Mitra J. Int. J. Biol. Macromol., 1985,7:336-348
21. [21]
  [21] Spek A L. PLATON, A Multipurpose Crystallographic Tool, The Netherlands, Utrecht University, 2001.
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沈阳化工大学材料科学与工程学院沈阳 110142