Citation: YE Jian, ZHANG Hai-Yan, CHEN Yi-Ming, HU Li, RAN Qi-Yan, DU Lei. Preparation of Graphene by Ball Milling-Assisted Oxidization-Reduction Method[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2523-2529. shu

Preparation of Graphene by Ball Milling-Assisted Oxidization-Reduction Method

1.
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: ZHANG Hai-Yan,
Received Date: 9 May 2012
Available Online: 11 June 2012
Fund Project: 国家自然科学基金(No.20971027)资助项目. (No.20971027)

Graphite oxide (GO) was prepared from natural graphite by a modified Hummers method. GO was firstly ball milled for 10 h and then exfoliated into graphene oxide by ultrasonication. Finally, graphene was prepared by magnetic mixing reflux method using hydrazine monohydrate as reductant. Graphene is characterized by SEM, AFM, XRD, Raman, FTIR, TEM measurements. The surface morphology and structure of graphene sheets which are prepared by low-energy ball milling assisted oxidization-reduction method and oxidization-reduction method without ball milling are compared and analyzed. The results show that ball milling contributes to the thinning and exfoliation of GO. Otherwise, low-energy ball milling can promote the reduction degree of GO, shorten the reflux reaction time and improve the efficiency of graphene preparation.
- graphene oxide;graphene;ball milling;ultrasonication;magnetic mixing
1. [1]
  [1] Soldano C, Mahmood A, Dujardin E. Carbon, 2010,48(8):2127-2150
2. [2]
  [2] Blake P, Brimicombe P D, Nair R R, et al. J. Nano Lett., 2008,8:1704-1708
3. [3]
  [3] Prasher R. Science, 2010,328(5975):185-186.
4. [4]
  [4] Novoselov K S, Geim A K, Morozov S V, et al. Science, 2004,306:666-669
5. [5]
  [5] Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007,45 (7):1558-1565
6. [6]
  [6] Stoller M D, Park S, Zhu Y W, et al. Nano Lett., 2008,8(10): 3498-3502
7. [7]
  [7] Kim K S, Zhao Y, Jang H, et al. Nature, 2009,475:706-710
8. [8]
  [8] Liu W, Chung C H, Miao C Q, et al. Thin Solid Films, 2010, 518:S128-S132
9. [9]
  [9] Park H J, Meyer J, Roth S, et al. Carbon, 2010,48:1088-1094
10. [10]
  [10] Reina A, Thiele S, Kong J, et al. Nano Res., 2009,2:509-516
11. [11]
  [11] Cai W W, Zhu Y W, Ruoff R S, et al. Appl. Phys. Lett., 2009,95:123115
12. [12]
  [12] Reina A, Jia X T, Kong J, et al. Nano Lett., 2009,9(1):30-35
13. [13]
  [13] Kosynkin D V, Higginbotham A L, Sinitskii A, et al. Carbon, 2009,46:3242-3246
14. [14]
  [14] Subrahmanyam K S, Panchakarla L S, Govindaraj A, et al. J. Phys. Chem., 2009,113(11):4257-4259
15. [15]
  [15] LV Yan(吕岩), WANG Zhi-Yong(王志永), ZHANG Hao(张浩), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2010,25 (7):725-728
16. [16]
  [16] Wu Z S, Ren W C, Gao L B, et al. ACS Nano, 2009,3(2): 411-417
17. [17]
  [17] Berger C, Song Z M, Li X B, et al. Science, 2006,312(5777): 1191-1196
18. [18]
  [18] Berger C, Song Z, Li T, et al. J. Phys. Chem., 2004,108(52): 19912-19916
19. [19]
  [19] Sutter P W, Flege J I, Sutter E A, et al. Nat. Mater., 2008,7 (5):406-411
20. [20]
  [20] McAllister M J, Li J L, Adamson D H, et al. Chem. Mater., 2007,19:4396-4404
21. [21]
  [21] Schniepp H C, Li J L, McAllister M J, et al. J. Phys. Chem. B, 2006,110:8535-8539
22. [22]
  [22] Lü W, Tang D M, He Y B, et al. ACS Nano, 2009,3(11): 3730-3736
23. [23]
  [23] Ye J, Zhang H Y, Hu L, et al. J. Power Source, 2012,212: 105-110
24. [24]
  [24] Zhu Y W, Murali S, Stoller M D, et al. Carbon, 2010,48(7): 2118-2122
25. [25]
  [25] ZOU Zheng-Guang(邹正光), YU Hui-Jiang(俞惠江), LONG Fei(龙飞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(9):1753-1757
26. [26]
  [26] Chen Y, Zhang X, Zhang D C, et al. Carbon, 2011,49:573-580
27. [27]
  [27] Liu C G, Yu Z N, Neff D, et al. Nano Lett., 2010,10(12): 4863-4868
28. [28]
  [28] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958,80 (6):1339-1339
29. [29]
  [29] Li L H, Chen Y, Behan G, et al. J. Mater. Chem., 2011,21: 11862
30. [30]
  [30] Geim A K, Novoselov K S. Nat. Mater., 2007,6:183-191
31. [31]
  [31] Tuinstra F, Koenig J L. J. Chem. Phys., 1970,53(3):1126-1130
32. [32]
  [32] Ferrari A C, Meyer, J C, Novoselov K S, et al. Phys. Rev. Lett., 2006,97:187401
33. [33]
  [33] Kudin K N, Ozbas B, Schniepp H C, et al. Nano Lett., 2008,8(1):36-41
34. [34]
  [34] Kaniyoor A, Baby T T, Ramaprabhu S. J. Mater. Chem., 2010,20:8467-8469
35. [35]
  [35] Jeong H K, Colakerol L, Jin M H, et al. J. Chem. Phys. Lett., 2008,460:499-502
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