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Citation: HAN Lu, ZHOU Ya-song, WEI Qiang, LUO Yi, WANG Jing-yu. Effect of acidity and hydrogenation ability on the hydrodenitrogenation performance of NiW/Al2O3 catalyst[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(10): 1233-1239. shu

Effect of acidity and hydrogenation ability on the hydrodenitrogenation performance of NiW/Al2O3 catalyst

  • 1.

    State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China

  • Corresponding author: ZHOU Ya-song, 
  • Received Date: 25 March 2014
    Available Online: 5 May 2014

    Fund Project: 国家自然科学基金(U1362203) (U1362203) 国家重点基础研究发展规划(973计划, 2010CB226903)。 (973计划, 2010CB226903)

  • NiW/Al2O3 catalysts for the hydrodenitrogenation of heavy oil were prepared by nickel-tungstate active metals located on Al2O3 with wetness impregnation. The effect of boric acid on the acidity and the effect of citric acid on the hydrogenation ability were studied. The results of NH3-TPD, HRTEM, H2-TPR and XPS showed that the addition of boric acid increased the proportion of strong and medium acid. The strong interaction between the support and metal has been weakened. Citric acid achieved moderate length of Ni-W-S active phases, increased the dispersion and the sulfidation degree of the metal on catalysts surface. NiW catalyst modified with boron acid and citric acid had outstanding HDN performance for Venezuela deasphalted oil, promoted the hydrogenation of aromatics and resin. It also had strong HDN abilities to basic and non-basic nitrogen compounds. The catalyst showed outstanding HDN performance of heavy oil.
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    1. [1]

      [1] FAN Y, BAO X J. Citric acid-assisted hydrothermal method for preparing NiW/USY-Al2O3 ultra deep hydro-desulfurization catalysts[J]. J Catal, 2011, 279(1): 27-35.

    2. [2]

      [2] SATO S, KUROKI M, SODESAWA T, NOZAKI F, MACIEL G E. Surface structure and acidity of alumina-boric catalysts[J]. J Mol Catal A: Chem, 1995, 104: 171-177.

    3. [3]

      [3] DING L H, ZHANG Z S, ZHENG Y, RING Z, CHEN J W. Effect of fluorine and boron modification on the HDS, HDN and HDA activity of hydrotreating catalysts[J]. Appl Catal A: Gen, 2006, 301(2): 241-250.

    4. [4]

      [4] HENSEN E J M, KOOYMAN P J, VAN DER MEER Y, VAN DER KRAAN A M, DE BEER V H J, VAN VEEN J A R, VAN SANTEN R A. The relation between morphology and hydrotreating activity for supported MoS2 particles[J]. J Catal, 2001, 199(2): 224-235.

    5. [5]

      [5] FUJIKAWA T. Highly active CoMo HDS catalyst for the production of clean diesel fuels[J]. Catal Surv Asia, 2006, 10(2): 89-97.

    6. [6]

      [6] SUNDARAMURTHY V, DALAI A K, ADJAYE J. The effect of phosphorus on hydrotreating property of NiMo/γ-Al2O3 nitride catalyst[J]. Appl Catal A: Gen, 2008, 335(1): 204-210.

    7. [7]

      [7] PALCHEVA R, KALUZA L, SPOJAKINA A, JIRATOVA K, TYULIEV G. NiMo/γ-Al2O3 catalysts from Ni heteropolyoxomolybdate and effect of alumina modification by B, Co, or Ni[J]. Chin J Catal, 2012, 33(4/6): 952-961.

    8. [8]

      [8] KRAUS H, PRINS R. Composition of impregnation solutions and wet impregnated Mo-P/γ-Al2O3 catalysts as investigated by 31P and 95Mo NMR[J]. J Catal, 1996, 164(2): 251-259.

    9. [9]

      [9] LEWANDOWSKI M, SARBAK Z. The effect of boron addition on hydrodesulfurization and hydrodenitrogenation activity of NiMo/Al2O3 catalysts[J]. Fuel, 2000, 79(5): 487-495.

    10. [10]

      [10] MAITY S K, LEMUS M, ANCHEYTA J. Effect of preparation methods and content of boron on hydrotreating catalytic activity[J]. Energy Fuels, 2011, 25(7): 3100-3107.

    11. [11]

      [11] SUN M Y, NICOSIA D, PRINS R. The effects of fluorine, phosphate and chelating agents on hydrotreating catalysts and catalysis[J]. Catal Today, 2003, 86(1/4): 173-189.

    12. [12]

      [12] 倪月琴, 憬龄, 赵瑛. 工业用加氢脱氮催化剂所含MoS2的形貌[J]. 催化学报, 1994, 15(6): 422-425. (NI Yue-qin, JING Ling, ZHAO Ying. The MoS2 morphology of industrial hydrodenitrogenation catalysts[J]. Chinese Journal of Catalysis, 1994, 15(6): 422-425.)

    13. [13]

      [13] XIANG C, CHAI Y M, LIU C G. Effect of phosphorus on the hydro-desulfurization and hydro-denitrogenation performance of presulfided NiMo/Al2O3 catalyst[J]. J Chem Phys, 2011, 39(5): 355-360.

    14. [14]

      [14] SCHEFFER B, HEIJEINGA J J, MOULIJIN J A. An electron spectroscopy and X-ray diffraction study of NiO/Al2O3 and WO3/Al2O3 catalysts[J]. J Phys Chem, 1987, 91(18): 4752-4759.

    15. [15]

      [15] MINGYONG S, BURGI T, CATTANEO R, VAN LANGEVELD D, PRINS R. TPS, XPS, QEXAFS and XANES investigation of the Sulfidation of NiW/Al2O3-F catalysts[J]. J Catal, 2001, 201(2): 258-269.

    16. [16]

      [16] QIU L M, XU G T. Peak overlaps and corresponding solutions in the X-ray photoelectron spectroscopic study of hydro-desulfurization catalysts[J]. Appl Surf Sci, 2010, 256(11): 3413-3417.

    17. [17]

      [17] BAKER M A, GILMORE R, LENARDI C, GISSLER W. XPS investigation of preferential sputtering of S from MoS2 and determination of MoSx stoichiometry from Mo and S peak positions[J]. Appl Surf Sci, 1999, 150(1/4): 255-262.

    18. [18]

      [18] TAYEB K B, LAMONIER C, LANCELOT C, FOURNIER M, BONDUELLE A, BERTONCINI F. Active phase genesis of NiW hydrocracking catalysts based on nickel salt heteropolytungstate: Comparison with reference catalyst[J]. Appl Catal B: Environ, 2012, 126: 55-63.

    19. [19]

      [19] YU G L, ZHOU Y S, WEI Q. A novel method for preparing well dispersed and highly sulfide NiW hydro-denitrogenation catalyst[J]. Catal Commun, 2012, 23: 48-53.

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